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This paper describes the results of Phase 1 of the Diesel Emission Control - Sulfur Effects (DECSE) Program. The objective of the program is to determine the impact of fuel sulfur levels on emissions control systems that could be used to lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from vehicles with diesel engines. The DECSE program has now issued four interim reports for its first phase, with conclusions about the effect of diesel sulfur level on PM and total hydrocarbon (THC) emissions from the high-temperature lean-NOx catalyst, the increase of engine-out sulfate emissions with higher sulfur fuel levels, the effect of sulfur content on NOx adsorber conversion efficiencies, and the effect of fuel sulfur content on diesel oxidation catalysts, causing increased PM emissions above engine-out emissions under certain operating conditions.

Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.

Alternative compression ignition engine fuels are of interest both to reduce emissions and to reduce U.S. petroleum fuel demand. A Malaysian Fischer-Tropsch gas-to-liquid fuel was compared with California #2 diesel by characterizing emissions from over the road Class 8 tractors with Caterpillar 3176 engines, using a chassis dynamometer and full scale dilution tunnel. The 5-Mile route was employed as the test schedule, with a test weight of 42,000 lb. Levels of oxides of nitrogen (NOx) were reduced by an average of 12% and particulate matter (PM) by 25% for the Fischer-Tropsch fuel over the California diesel fuel. Another distillate fuel produced catalytically from Fischer-Tropsch products originally derived from natural gas by Mossgas was also compared with 49-state #2 diesel by characterizing emissions from Detroit Diesel 6V-92 powered transit buses, three of them equipped with catalytic converters and rebuilt engines, and three without.

Stringent regulations on fuel economy have driven major innovative changes in the internal combustion engine design. (E.g. CAFE fuel economy standards of 54.5 mpg by 2025 in the U.S) Vehicle manufacturers have implemented engine infrastructure changes such as downsizing, direct injection, higher compression ratios and turbo-charging/super-charging to achieve higher engine efficiencies. Fuel properties therefore, have to align with these engine changes in order to fully exploit the possible benefits. Fuel octane number is a key metric that enables high fuel efficiency in an engine. Greater resistance to auto-ignition (knock) of the fuel/air mixture allows engines to be operated at a higher compression ratio for a given quantity of intake charge without severely retarding the spark timing resulting in a greater torque per mass of fuel burnt. This attribute makes a high octane fuel a favorable hydrocarbon choice for modern high efficiency engines that aim for higher fuel economy.

Diesel particulate filter (DPF) is necessary for diesel engines to meet the increasingly stringent emission regulations. Many studies have demonstrated that the lubricant derived ash has a significant effect on DPF pressure drop and engine fuel economy, and this effect becomes more and more severe with the increasing of operating hours of the DPF because the ash accumulated in the DPF cannot be removed by regeneration. It is reported that most of the DPFs operated with more ash than soot in the filter for more than three quarters of the time during its lifetime [1]. In order to mitigate this problem, the original engine manufacturers (OEM) tend to use an oversized DPF for the engine. However, it will increase the costs of the DPF and reduce the compactness of the engine aftertreatment system.

In this study a 1-dimensional computational model of a Fe-Zeolite catalyst, implementing conservation of mass, species and energy for both gas and catalyst surface phases has been developed to simulate emissions conversion performance. It is applied to both a fresh catalyst and one that has been aged through exposure to the exhaust system of a Heavy Duty Diesel engine performing in the field for 376K miles. Details of the chemical kinetics associated with the various NOx reduction reactions in the two Fe-Zeolite configurations have been examined and correlated with data from a synthetic gas rig test bench. It was found that the Standard reaction, (4NH3 + 4NO + O2 → 2N2 + 6H2O), which is one of the main reactions for NOx reduction, degraded significantly at the lower temperatures for the aged system.

The National Renewable Energy Laboratory’s (NREL’s) CoolSim MATLAB/Simulink modeling framework was used to explore control strategies for an electric vehicle combined loop system. Three system variants of increased complexity and efficiency were explored: a glycol-based positive temperature coefficient heater (PTC), PTC with power electronics and electric motor (PEEM) waste heat recovery, and PTC with PEEM waste heat recovery plus heat pump versions. Additionally, the benefit of electric motor preheating was considered. A two-level control strategy was developed where the mode selection and component control were treated separately. Only the parameters typically available by vehicle sensors were used to control the system. The control approach included a mode selection algorithm and controllers for the compressor speed, cabin blower flow rate, coolant flow rate, and the front-end heat exchanger coolant bypass rate.

“Gas-to-liquids” catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude-derived fuels. Methylal (CH3-O-CH2-O-CH3), also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins B5.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions.

A relationship has been observed between increasing ethanol content in gasoline and increased particulate matter (PM) emissions from direct injection spark ignition (DISI) vehicles. The fundamental cause of this observation is not well understood. One potential explanation is that increased evaporative cooling as a result of ethanol’s high HOV may slow evaporation and prevent sufficient reactant mixing resulting in the combustion of localized fuel rich regions within the cylinder. In addition, it is well known that ethanol when blended in gasoline forms positive azeotropes which can alter the liquid/vapor composition during the vaporization process. In fact, it was shown recently through a numerical study that these interactions can retain the aromatic species within the liquid phase impeding the in-cylinder mixing of these compounds, which would accentuate PM formation upon combustion.

The National Renewable Energy Laboratory’s (NREL’s) CoolSim MATLAB/Simulink modeling framework was expanded by including a newly developed coolant loop solution method aimed at reducing the simulation effort for complex thermal management systems. The new approach does not require the user to identify specific coolant loops and their flow. The user only needs to connect the fluid network elements in a manner consistent with the desired schematic. Using the new solution method, a model of NREL's advanced combined coolant loop system for electric vehicles was created that reflected the test system architecture. This system was built using components provided by MAHLE Inc. and included both air conditioning and heat pump modes. Validation with test bench data and verification with the previous solution method were performed for 10 operating points spanning a range of ambient temperatures between -2°C and 43°C.

Worldwide, Fuel Economy (FE) legislation increasingly influences vehicle and engine design, and drives friction reduction. The link between lubricant formulation and mechanical friction is complex and depends on engine component design and test cycle. This Motored Friction Tear Down (MFTD) study characterizes the friction within a 3.6L V6 engine under operating conditions and lubricant choices relevant to the legislated FE cycles. The high-fidelity MFTD results presented indicate that the engine is a low-friction engine tolerant of low viscosity oils. Experiments spanned four groups of engine hardware (reciprocating, crankshaft, valvetrain, oil pump), five lubricants (four candidates referenced against an SAE 0W-20) and five temperature regimes. The candidate lubricants explored the impact of base oil viscosity, viscosity modifier (VM) and friction modifier (FM) content.

A multi-year technology validation program was completed in 2001 to evaluate ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different diesel fleets operating in Southern California. The fuels used throughout the validation program were diesel fuels with less than 15-ppm sulfur content. Trucks and buses were retrofitted with two types of passive DPFs. Two rounds of emissions testing were performed to determine if there was any degradation in the emissions reduction. The results demonstrated robust emissions performance for each of the DPF technologies over a one-year period. Detailed descriptions of the overall program and results have been described in previous SAE publications [2, 3, 4, 5]. In 2002, a third round of emission testing was performed by NREL on a small subset of vehicles in the Ralphs Grocery Truck fleet that demonstrated continued robust emissions performance after two years of operation and over 220,000 miles.

This research focuses on the technical issues that are critical to the adoption of high-energy-producing lithium Ion batteries. In addition to high energy density / high power density, this publication considers performance requirements that are necessary to assure lithium ion technology as the battery format of choice for electrified vehicles. Presentation of prime topics includes: • Long calendar life (greater than 10 years) • Sufficient cycle life • Reliable operation under hot and cold temperatures • Safe performance under extreme conditions • End-of-life recycling To achieve aggressive fuel economy standards, carmakers are developing technologies to reduce fuel consumption, including hybridization and electrification. Cost and affordability factors will be determined by these relevant technical issues which will provide for the successful implementation of lithium ion batteries for application in future generations of electrified vehicles.

Among on-road motor vehicles, diesel-fueled heavy-duty trucks emit disproportionately high amounts of oxides of nitrogen (NOx) and particulate matter (PM). The trucking industry has taken an active interest in the use of engines powered by liquefied natural gas (LNG) to reduce NOx and PM emissions. However, major barriers exist to widespread use of LNG in trucking applications, including reduced performance and higher initial capital costs compared to diesel-fueled vehicles, as well as a limited fueling infrastructure. To help address these barriers, the California Energy Commission (Commission) joined with the South Coast Air Quality Management District (SCAQMD) and the U.S. Department of Energy's National Renewable Energy Laboratory (DOE/NREL) in cost sharing a program led by the West Coast Transportation Technology Group of Arthur D. Little, Inc. (ADLittle).

Several high octane number oxygenates that could be derived from biomass were blended with gasoline and examined for performance properties and their impact on knock resistance and fine particle emissions in a single cylinder direct-injection spark-ignition engine. The oxygenates included ethanol, isobutanol, anisole, 4-methylanisole, 2-phenylethanol, 2,5-dimethyl furan, and 2,4-xylenol. These were blended into a summertime blendstock for oxygenate blending at levels ranging from 10 to 50 percent by volume. The base gasoline, its blends with p-xylene and p-cymene, and high-octane racing gasoline were tested as controls. Relevant gasoline properties including research octane number (RON), motor octane number, distillation curve, and vapor pressure were measured. Detailed hydrocarbon analysis was used to estimate heat of vaporization and particulate matter index (PMI). Experiments were conducted to measure knock-limited spark advance and particulate matter (PM) emissions.

Chassis dynamometer testing of two 60 foot articulated transit busses, one conventional and one hybrid, was conducted at the National Renewable Energy Laboratory's, ReFUEL facility. Both test vehicles were 2004 New Flyer busses powered by Caterpillar C9 8.8L engines, with the hybrid vehicle incorporating a GM-Allison advanced hybrid electric drivetrain. Both vehicles also incorporated an oxidizing diesel particulate filter. The fuel economy and emissions benefits of the hybrid vehicle were evaluated over four driving cycles; Central Business District (CBD), Orange County (OCTA), Manhattan (MAN) and a custom test cycle developed from in-use data of the King County Metro (KCM) fleet operation. The hybrid vehicle demonstrated the highest improvement in fuel economy (mpg basis) over the low speed, heavy stop-and-go driving conditions of the Manhattan test cycle (74.6%) followed by the OCTA (50.6%), CBD (48.3%) and KCM (30.3%).

Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.

This work details two approaches for evaluating transmission warming technology: experimental dynamometer testing and development of a simplified transmission efficiency model to quantify effects under varied real world ambient and driving conditions. Two vehicles were used for this investigation: a 2013 Ford Taurus and a highly instrumented 2011 Ford Fusion (Taurus and Fusion). The Taurus included a production transmission warming system and was tested over hot and cold ambient temperatures with the transmission warming system enabled and disabled. A robot driver was used to minimize driver variability and increase repeatability. Additionally the instrumented Fusion was tested cold and with the transmission pre-heated prior to completing the test cycles. These data were used to develop a simplified thermally responsive transmission model to estimate effects of transmission warming in real world conditions.

Piston ring and liner wear measurements and analyses were performed in a production 3.6L V6 gasoline engine with radiolabelled engine parts. Three isotopes were generated: one in the engine liner using surface layer activation; one each in the top ring face and top ring side using bulk activation. Real-time wear measurements and subsequent rates of these three surfaces were captured using the radioactive decay of the isotopes into the engine oiling system. In addition, surface roughness and wear profile measurements were carried out using white light interferometry. The results from Phase I provided insights on evolution of wear and wear rates in critical engine components in a gasoline engine. Phase II will extend this work further and focus on evaluating the fuel additive effects on engine wear.

Laminar burning velocity is a fundamental combustion property of any fuel/air mixture. Formulating gasoline fuel blends having faster burning velocities can be an effective strategy for enhancing engine and vehicle performance. Formulation of faster burning fuels by changing the fuel composition has been explored in this work leading to a clear correlation between engine performance and fuel burning velocity. In principle a gasoline vehicle should be calibrated to give optimal ignition timing (also known as MBT - minimum spark advance for best torque) while at the same time avoiding any possible engine knock. However, modern downsized/boosted engines frequently tend to be limited by knock and the spark timing is retarded in respect of the optimum. In such scenarios, faster burning fuels can lead to a more optimum combustion phasing resulting in a more efficient energy transfer and hence a faster acceleration and better performance.